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Surfactant

Sorbitan monooleate CAS 1338-43-8

Sorbitol monoleate, also known as sorbitol anhydride monoleate, can be used as a non-ionic surfactant.
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Description
Sorbitan monooleate Properties
Overview of Sorbitan Monooleate
Sorbitan monooleate, also known as sorbitan monooleate, can be used as a nonionic surfactant.
Span-80 is a yellow oily liquid, easily soluble in water, ethanol, methanol or ethyl acetate, and very slightly soluble in mineral oil. It is a w/o type emulsifier, which has strong emulsification, chemical dispersion and lubrication effects. It can be mixed with various surfactants, especially suitable for Tween-60, and the effect is better when used in combination. HLB value is 4.7, melting point is 52-57℃.

Properties of Sorbitan Monooleate
Boiling Point: 463.43°C (rough estimate)
Density: 0.986g/ml at 25°C(lit.)
Vapor Pressure: <1.4hPa(20°C)
Refractive Index: n20/D1.48(lit.)
Flash Point: >230°F
Storage Conditions: Store below +30°C
Solubility: Almost insoluble in water, but can be dispersed in water, soluble in fatty oils to produce a turbid solution, and miscible with alcohol.
Form: Viscous liquid
Proportion: 0.986
Color: Yellow
Odor: Fatty oily waxy smell
Fragrance Type: Fatty
Water Solubility: Soluble in ethanol at 50mg/ml Miscible with water, ethanol, isopropanol and ether, Insoluble in acetone.

Performance of Sorbitan Monooleate
Using sorbitol as raw material, dehydration and ring-closure are performed to generate sorbitol, which is then esterified with oleic acid. An amber viscous oily substance with oily properties, relative density of 1.029, and melting point of 10-12°C. It has a fat smell, is insoluble in water, can be dispersed in hot water, and is soluble in organic solvents. It is a nonionic surfactant with an HLB value of 4.3. It has emulsification, solubilization and diffusion capabilities, as well as defoaming and stabilizing effects. It is not soluble in isopropyl alcohol, tetrachlorethylene, xylene, cottonseed oil, mineral oil, etc. It is a high-grade lipophilic emulsifier.

Production Methods of Sorbitan Monooleate
Add 70% sorbitol into the stainless steel reactor, add 0.6% mass dehydration catalyst (phosphoric acid or p-toluenesulfonic acid), alcohol: acid = 1: (1.5~1.7) (molar ratio), and heat up to below 150°C , lose water for 3 hours; then add oleic acid preheated to 90% and 0.3% mass esterification catalyst (KOH or NaOH) into the dehydrated sorbitol, and raise the temperature to 210°C under nitrogen filling for 4 to 5 hours; when When the acid value is less than 8mgKOH/g, the reaction ends; the product is obtained after standing, cooling and filtering.
Put 88kg of sorbitol into the reaction kettle and dehydrate under reduced pressure. After dehydration is completed, press in 130kg of refined oleic acid and an appropriate amount of sodium hydroxide (as a catalyst). Start stirring, evacuate, slowly raise the temperature, and react at 200~210°C for 6 hours. Take a sample and measure the acid value. When the acid value is 6 to 7, the esterification reaction is completed. Cool down and let it stand for 24 hours. After letting it stand, it is divided into upper and lower layers. The lower layer is a black gelatinous substance. Separate and discard it. Pour the upper clarified liquid into the decolorizing kettle, heat it to about 65°C and decolorize with activated carbon, and decolorize at 80-85°C for 1 hour. Filter, and the filtrate is dehydrated under vacuum for 5 hours to obtain the finished product.

Technical Parameter of Sorbitan Monooleate
 
Product Name Short Name Active matter content HLB Melting point Appearance
Sorbitan monooleate N/A N/A 4.3 10-12 the amber viscous oily substance

Application of Sorbitan Monooleate
1. Used as emulsifier, stabilizer, thickener, and wetting agent in medicine, cosmetics, and textile industries. It can also be used as dispersant in paint industry and emulsifier in oil fields.
2. Emulsion explosives, petroleum, medicine, cosmetics, textiles, paint, leather and other industries
3. Gas chromatography stationary solution, also used as emulsifier

4. W/O food emulsifier, used alone or mixed with Tween-60, Tween-80, and Tween-65. China stipulates that it can be used in vegetable protein beverages, milk, hydrogenated vegetable oil, bread, pastries and toffee, with a maximum dosage of 1.5g/kg; in fruit juice (flavored) beverages, the maximum dosage is 0.05g/kg. In addition, it can also be used for the preservation (coating) of vegetables and fruits, and can be used in appropriate amounts according to production needs.
5. Nonionic surfactants can be used to form oil-in-water emulsions, and can be combined with low HLB surfactants to form water-in-oil emulsions.
6. Good oil-in-water emulsifier. Gas chromatography stationary solution (maximum operating temperature 150°C, solvent is methanol), separates and analyzes oxygenated compounds. stabilizer. Thickening agent for food, cosmetics and drugs. Fiber lubricants and softeners for the textile industry.

Company Profile
Luoyang Tongrun Nano Technology Co. Ltd. (TRUNNANO) is a trusted global chemical material supplier & manufacturer with over 12-year-experience in providing super high-quality chemicals and nanomaterials, including boride powder, nitride powder, graphite powder, sulfide powder, 3D printing powder, etc.
The company has a professional technical department and Quality Supervision Department, a well-equipped laboratory, and equipped with advanced testing equipment and after-sales customer service center.
If you are looking for high-quality Sorbitan Monooleate, please feel free to contact us or click on the needed products to send an inquiry. 


Packing of Sorbitan Monooleate
1kg/bottle, 25kg/barrel, or 200kg/barrel.
We have many different kinds of packing which depend on the quantity.

Payment Methods of Sorbitan Monooleate
L/C, T/T, Western Union, Paypal, Credit Card etc.

Shipment of Sorbitan Monooleate
By sea, by air, by express as soon as possible once payment receipt.

Sorbitan monooleate Properties

Other Names Span 80; S - 80. Sorbitan monoleate
CAS No. 1338-43-8
Compound Formula C24H44O6
Molecular Weight N/A
Appearance amber viscous oily substance
Melting Point N/A
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass N/A

Sorbitan monooleate Health & Safety Information

Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Statements N/A
Transport Information
N/A
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