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High-quality semiconductor material-gallium oxide

Views : 450
Author : TRUNNANO
Update time : 2021-04-14 14:11:57
What is gallium nitride?
Heating metal gallium in the air to oxidize it or calcining gallium nitrate at 200-250°C, gallium hydroxide and some gallium compounds can form Ga2O3. Ga2O3 has five isomers: α, β, γ, δ, ε, of which the most stable is β-isomer. When heated to above 1000℃ or hydrothermally heated to above 300℃, all others The isomers of are converted to β-isomers. A variety of pure substitutes can be prepared in different ways.
Alpha-Ga2O3 can be obtained by heating metallic gallium in the air to 420~440°C; calcining nitrate to decompose it or heating gallium hydroxide to 500°C.
Quickly heating the hydroxide gel to 400500℃ can be worthy of γ-Ga2O3, which has a defective spinel structure.
Heating gallium nitrate at 250°C and then immersing it at about 200°C for 12 hours can produce δ-Ga2O3, which is similar to the C-structure of In2O3, Tl2O3, Mn2O3 and Ln2O3.
Ε-Ga2O3 can be obtained by heating δ-Ga2O3 briefly at 550°C (about 30 minutes).
Nitrate, acetate, oxalate or other gallium compounds and any other isomers of Ga2O3 can be decomposed or converted into β-Ga2O3 when heated to above 1000°C.

What type of substance is gallium oxide?
Gallium oxide is a highly insoluble, thermally stable source of gallium suitable for glass, optical and ceramic applications. The precipitation of gallium oxide in hydrated form is caused by the neutralization of acidic or alkaline gallium salt solutions. Oxide does not conduct electricity.

Is gallium oxide acidic or alkaline?
Gallium oxide (Ga2O3) is an amphoteric oxide. The reason is that gallium is amphoteric (that is, it reacts in the form of acid or alkali depending on the situation), and reacts with sodium hydroxide and potassium hydroxide solutions to form gallate and hydrogen.

Is gallium oxide a semiconductor?
Gallium oxide is a semiconductor material with a larger bandgap than silicon, gallium nitride and silicon carbide, but it will require more research and development before it can become a major player in power electronics. The bandgap measures how much energy is required to oscillate an electron into a conductive state.

Gallium oxide with unlimited possibilities in the semiconductor industry
In addition, gallium oxide has a nice feature, that is, you can add charge carriers to it to make it more conductive through a process called doping. Doping involves adding controlled amounts of impurities to the crystal to control the concentration of charge carriers in the semiconductor. For example, in silicon, you can use ion implantation and then annealing to dope the crystal with phosphorus (add free electrons) or boron (subtract them) so that charges can move freely in it. In Ga2O3, you can add electrons in a similar way.
Among the five characteristics that are critical to semiconductors, the high critical electric field strength is the biggest advantage of β-gallium oxide. This helps to create high-voltage switches and may mean that powerful RF devices can be designed based on them. However, the biggest disadvantage of β-gallium oxide is its low thermal conductivity, which means that heat may be trapped inside the device.
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